• Deepika Padukone
• Mastani | -
• Mastani
• -

• Priyanka Chopra
• Kashibai | -
• Kashibai
• -

• Ranveer Singh
• Bajirao | -
• Bajirao
• -

• Tanvi Azmi
• Radhabai - Bajirao's mother | -
• Radhabai - Bajirao's mother
• -

• Mahesh Manjrekar
• Maratha King | -
• Maratha King
• -

• Raza Murad
• Nizam of Deccan | -
• Nizam of Deccan
• -

• Aditya Pancholi
• Panth Pratinidhi | -
• Panth Pratinidhi
• -

• Vaibbhav Tatwawdi
• Chimaji Appa, Bajirao's younger brother | -
• Chimaji Appa, Bajirao's younger brother
• -

• Milind Soman
• Ambaji Panth | -
• Ambaji Panth
• -

• Benjamin Gilani
• Raja Chhatrasaal | -
• Raja Chhatrasaal
• -

• Ganesh Yadav
• Malhar Rao | -
• Malhar Rao
• -

• Irrfan Khan
• - | Narrator (Voice-over)
• -
• Narrator (Voice-over)